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预防医学  2021, Vol. 33 Issue (3): 246-249,254    DOI: 10.19485/j.cnki.issn2096-5087.2021.03.007
  论著 本期目录 | 过刊浏览 | 高级检索 |
食品包装纸中11种DSD-FWAs的迁移试验
何华丽, 樊继彩, 王小芳, 任韧
杭州市疾病预防控制中心卫生检验中心,浙江 杭州 310021
Migration of eleven DSD-FWAs from packaging paper to food
HE Huali, FAN Jicai, WANG Xiaofang, REN Ren
Health Inspection Center, Hangzhou Center for Disease Control and Prevention, Hangzhou, Zhejiang 310021, China
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摘要 目的 观察食品包装纸中11种双三嗪氨基二苯乙烯类荧光增白剂(DSD-FWAs)迁移情况,为食品包装纸的质量安全监管提供依据。方法 收集41份DSD-FWAs阳性的食品包装纸样品,剪成表面积为6 cm2的纸片,分别浸泡于10 mL的蒸馏水、3%乙酸、10%乙醇和95%乙醇4种食品模拟物中,在特定时间和温度下进行迁移试验;采用高效液相色谱-荧光检测(HPLC-FLD)法检测11种DSD-FWAs迁移量。结果 4种食品模拟物中均检出C.I.220、C.I.24、C.I.210、C.I.85、C.I.113、C.I.264、C.I.353和C.I.357。在相同温度和时间下,迁移量从大到小依次为10%乙醇、蒸馏水、3%乙酸和95%乙醇。C.I.220在4种食品模拟物中均有溶出,在20~90 ℃浸泡温度下,迁移量随浸泡温度升高而增加;在20、40、60 ℃浸泡温度下,C.I.220在4种食品模拟物中的迁移量随时间延长均呈快速上升后平稳的趋势。结论 食品包装纸的储存温度越高、保存时间越长,包装纸中的DSD-FWAs越容易向食品迁移。
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何华丽
樊继彩
王小芳
任韧
关键词 双三嗪氨基乙烯类荧光增白剂食品包装纸食品模拟物迁移量    
AbstractObjective To observe the migration of 4,4'-diaminostilbene-2,2'-disulfonc acid-based fluorescent whitening agents ( DSD-FWAs ) in food packaging paper, so as to provide evidence for quality and safety supervision for paper packaging materials. Methods Forty-one paper samples with DSD-FWAs positive were made into 6 cm2 pieces and were soaked in four food simulants ( distilled water, 3% acetic acid, 10% ethanol and 95% ethanol, 10 mL each ). The experiment was carried out at the specified soaking temperature and time. The migration amounts of eleven DSD-FWAs were detected by high performance liquid chromatography-fluorescence detection. Results C.I.220, C.I.24, C.I.210, C.I.85, C.I.113, C.I.264, C.I.353 and C.I.357 were found in all the four food simulants. At the same time and temperature, the migration amount was highest in 10% ethanol, followed by distilled water, 3% acetic acid and 95% ethanol. C.I.220 was dissolved in all four food simulants, in the range of 20-90 ℃, the migration amount increased with soaking temperature; at 20 ℃, 40 ℃ and 60 ℃, the migration amount increased first and then stabilized over time. Conclusion The higher the storage temperature and the longer the storage time of paper packaging, the easier the DSD-FWAs in packaging paper migrate to food.
Key words4,4'-diaminostilbene-2,2'-disulfonc acid-based fluorescent whitening agents    food packing paper    food simulator    migration amount
收稿日期: 2020-09-08      修回日期: 2020-12-09      出版日期: 2021-03-10
中图分类号:  R155  
基金资助:杭州市农业与社会发展科研计划项目(20170533B74)
通信作者: 何华丽,E-mail:hhlzjut1989@163.com   
作者简介: 何华丽,硕士,主管技师,主要从事食品安全理化检验工作
引用本文:   
何华丽, 樊继彩, 王小芳, 任韧. 食品包装纸中11种DSD-FWAs的迁移试验[J]. 预防医学, 2021, 33(3): 246-249,254.
HE Huali, FAN Jicai, WANG Xiaofang, REN Ren. Migration of eleven DSD-FWAs from packaging paper to food. Preventive Medicine, 2021, 33(3): 246-249,254.
链接本文:  
http://www.zjyfyxzz.com/CN/10.19485/j.cnki.issn2096-5087.2021.03.007      或      http://www.zjyfyxzz.com/CN/Y2021/V33/I3/246
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